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116 five letter words begin with PE, and the third box leans toward R and A more than anything else.
R leads at about seventeen percent, A at fourteen and N at thirteen. A second E takes ten, then T at nine.
PEACE, PEARL, PEAKS and PEACH all run PEA, and between them they hold most of what a player would guess from this group.
PENNY, PEERS, PEDAL, PESTS and PETTY cover the other branches, and none of them shares much with the PEA family beyond the opening pair.
PEACE is the sensible opener. It covers the busiest three letter shape and its C and E are common enough that a miss still narrows the field.
PEARL. Its R and L reach two separate branches while the CH in PEACH appears in very little else here.
PEERS and PEEKS among others. At ten percent it is worth testing once the A and R shapes have failed.
A fair share, clustered on the R and T branches. The count is real but the playable list is shorter.